{"id":9926,"date":"2025-06-14T09:31:20","date_gmt":"2025-06-14T01:31:20","guid":{"rendered":"https:\/\/www.51malin.com\/index.php\/archives\/9926"},"modified":"2025-06-14T09:31:20","modified_gmt":"2025-06-14T01:31:20","slug":"%e5%88%86%e6%9e%90%e8%80%90%e6%b0%b4%e8%a7%a3%e9%87%91%e5%b1%9e%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e6%88%90%e6%9c%ac%e6%95%88%e7%9b%8a%e4%b8%8e%e5%b8%82%e5%9c%ba%e5%ba%94%e7%94%a8","status":"publish","type":"post","link":"https:\/\/www.51malin.com\/index.php\/archives\/9926","title":{"rendered":"\u5206\u6790\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6210\u672c\u6548\u76ca\u4e0e\u5e02\u573a\u5e94\u7528"},"content":{"rendered":"<h1>\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\uff1a\u6210\u672c\u6548\u76ca\u4e0e\u5e02\u573a\u5e94\u7528\u5168\u666f\u89e3\u6790<\/h1>\n<p>\u5728\u5316\u5de5\u3001\u5236\u836f\u3001\u73af\u4fdd\u7b49\u591a\u4e2a\u9886\u57df\uff0c\u50ac\u5316\u5242\u72b9\u5982\u4e00\u4f4d\u201c\u5316\u5b66\u754c\u7684\u9b54\u6cd5\u5e08\u201d\uff0c\u5b83\u80fd\u52a0\u901f\u53cd\u5e94\u901f\u7387\u800c\u4e0d\u6539\u53d8\u81ea\u8eab\u6027\u8d28\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0c<strong>\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242<\/strong>\uff08Hydrolysis-Resistant Metal Catalysts\uff09\u8fd1\u5e74\u6765\u9010\u6e10\u5d2d\u9732\u5934\u89d2\uff0c\u6210\u4e3a\u79d1\u7814\u754c\u548c\u5de5\u4e1a\u754c\u4e89\u76f8\u8ffd\u6367\u7684\u201c\u9999\u997d\u997d\u201d\u3002\u8fd9\u7bc7\u6587\u7ae0\u5c06\u5e26\u4f60\u8d70\u8fdb\u8fd9\u7c7b\u50ac\u5316\u5242\u7684\u4e16\u754c\uff0c\u4ece\u5b83\u4eec\u7684\u57fa\u672c\u7279\u6027\u3001\u6210\u672c\u6548\u76ca\u5206\u6790\u5230\u5e02\u573a\u5e94\u7528\u73b0\u72b6\uff0c\u518d\u5230\u672a\u6765\u53d1\u5c55\u8d8b\u52bf\uff0c\u4e00\u5e94\u4ff1\u5168\u3002<\/p>\n<hr \/>\n<h2>\u4e00\u3001\u4ec0\u4e48\u662f\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\uff1f<\/h2>\n<p>\u7b80\u5355\u6765\u8bf4\uff0c<strong>\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242<\/strong>\u662f\u4e00\u7c7b\u5728\u542b\u6c34\u73af\u5883\u4e2d\u4ecd\u80fd\u4fdd\u6301\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6d3b\u6027\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u3002\u4f20\u7edf\u7684\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u6c34\u4e2d\u5bb9\u6613\u53d1\u751f\u6c34\u89e3\u53cd\u5e94\uff0c\u5bfc\u81f4\u7ed3\u6784\u7834\u574f\u3001\u6d3b\u6027\u4e0b\u964d\u751a\u81f3\u5931\u6d3b\u3002\u800c\u8010\u6c34\u89e3\u578b\u5219\u901a\u8fc7\u6750\u6599\u8bbe\u8ba1\u3001\u914d\u4f53\u4fee\u9970\u6216\u8f7d\u4f53\u4f18\u5316\u7b49\u624b\u6bb5\uff0c\u6709\u6548\u63d0\u5347\u4e86\u5176\u5728\u6c34\u6027\u4f53\u7cfb\u4e2d\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n<h3>\u5e38\u89c1\u7c7b\u578b\u53ca\u4ee3\u8868\u7269\u8d28\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u7c7b\u578b<\/th>\n<th>\u4ee3\u8868\u50ac\u5316\u5242<\/th>\n<th>\u7279\u70b9<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u94af\u57fa\u50ac\u5316\u5242<\/td>\n<td>Pd\/C, Pd(OAc)\u2082<\/td>\n<td>\u6c22\u5316\u53cd\u5e94\u8868\u73b0\u4f18\u5f02<\/td>\n<\/tr>\n<tr>\n<td>\u94f1\u57fa\u50ac\u5316\u5242<\/td>\n<td>[Ir(cod)Cl]\u2082<\/td>\n<td>\u6c22\u8f6c\u79fb\u53cd\u5e94\u6548\u7387\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u948c\u57fa\u50ac\u5316\u5242<\/td>\n<td>RuCl\u2083\u00b7xH\u2082O<\/td>\n<td>\u5bf9\u6c27\u5316\u8fd8\u539f\u73af\u5883\u9002\u5e94\u6027\u5f3a<\/td>\n<\/tr>\n<tr>\n<td>\u9507\u57fa\u50ac\u5316\u5242<\/td>\n<td>OsO\u2084<\/td>\n<td>\u73af\u6c27\u5316\u53cd\u5e94\u5e38\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u914d\u4f53\u4fee\u9970\u578b\u50ac\u5316\u5242<\/td>\n<td>BINAP-Pd, Xantphos-Ru<\/td>\n<td>\u624b\u6027\u5408\u6210\u4e2d\u8868\u73b0\u51fa\u8272<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udca1\u5c0f\u8d34\u58eb\uff1a\u5982\u679c\u4f60\u5728\u505a\u6709\u673a\u5408\u6210\u65f6\u53d1\u73b0\u50ac\u5316\u5242\u5728\u6c34\u91cc\u201c\u6ce1\u6c64\u201d\u4e86\u8fd8\u7167\u6837\u5e72\u6d3b\uff0c\u90a3\u606d\u559c\u4f60\uff0c\u53ef\u80fd\u5df2\u7ecf\u7528\u4e0a\u4e86\u8010\u6c34\u89e3\u578b\uff01<\/p>\n<hr \/>\n<h2>\u4e8c\u3001\u4e3a\u4ec0\u4e48\u6211\u4eec\u9700\u8981\u8010\u6c34\u89e3\u50ac\u5316\u5242\uff1f<\/h2>\n<p>\u4f20\u7edf\u50ac\u5316\u5242\u5728\u975e\u6781\u6027\u6eb6\u5242\u4e2d\u8868\u73b0\u826f\u597d\uff0c\u4f46\u4e00\u65e6\u9047\u5230\u6c34\u2014\u2014\u5c24\u5176\u662f\u9178\u6027\u6216\u78b1\u6027\u6c34\u6eb6\u6db2\uff0c\u5c31\u5bb9\u6613\u201c\u7ffb\u8f66\u201d\u3002\u8fd9\u4e0d\u4ec5\u5f71\u54cd\u50ac\u5316\u6548\u7387\uff0c\u8fd8\u53ef\u80fd\u5bfc\u81f4\u526f\u4ea7\u7269\u589e\u591a\u3001\u50ac\u5316\u5242\u56de\u6536\u56f0\u96be\u7b49\u95ee\u9898\u3002<\/p>\n<p>\u800c\u73b0\u4ee3\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\u8d8b\u52bf\u4e4b\u4e00\u5c31\u662f<strong>\u51cf\u5c11\u6709\u6bd2\u6eb6\u5242\u7684\u4f7f\u7528<\/strong>\uff0c\u63a8\u52a8\u4ee5\u6c34\u4e3a\u4ecb\u8d28\u7684\u53cd\u5e94\u4f53\u7cfb\u3002\u8fd9\u5c31\u5bf9\u50ac\u5316\u5242\u63d0\u51fa\u4e86\u66f4\u9ad8\u7684\u8981\u6c42\uff1a<strong>\u65e2\u8981\u9ad8\u6548\uff0c\u53c8\u8981\u6297\u6c34\u89e3<\/strong>\u3002<\/p>\n<h3>\u8010\u6c34\u89e3\u50ac\u5316\u5242\u7684\u4f18\u52bf\u603b\u7ed3\uff1a<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u4f18\u52bf\u9879\u76ee<\/th>\n<th>\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u7a33\u5b9a\u6027\u5f3a<\/td>\n<td>\u5728\u6c34\u6027\u4f53\u7cfb\u4e2d\u4e0d\u6613\u5206\u89e3<\/td>\n<\/tr>\n<tr>\n<td>\u53cd\u5e94\u6761\u4ef6\u6e29\u548c<\/td>\n<td>\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u8fdb\u884c\uff0c\u8282\u80fd\u53c8\u73af\u4fdd<\/td>\n<\/tr>\n<tr>\n<td>\u6613\u4e8e\u5206\u79bb\u56de\u6536<\/td>\n<td>\u591a\u6570\u53ef\u8d1f\u8f7d\u5728\u56fa\u76f8\u8f7d\u4f53\u4e0a\uff0c\u4fbf\u4e8e\u5faa\u73af\u5229\u7528<\/td>\n<\/tr>\n<tr>\n<td>\u7eff\u8272\u5316\u5b66\u53cb\u597d<\/td>\n<td>\u51cf\u5c11\u6709\u673a\u6eb6\u5242\u4f7f\u7528\uff0c\u7b26\u5408\u53ef\u6301\u7eed\u53d1\u5c55\u9700\u6c42<\/td>\n<\/tr>\n<tr>\n<td>\u9002\u7528\u8303\u56f4\u5e7f<\/td>\n<td>\u9002\u7528\u4e8e\u52a0\u6c22\u3001\u6c27\u5316\u3001\u5076\u8054\u7b49\u591a\u79cd\u53cd\u5e94<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udf31\u4e00\u53e5\u8bdd\u603b\u7ed3\uff1a\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u7eff\u8272\u5316\u5b66\u7684\u201c\u597d\u5e2e\u624b\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e09\u3001\u6210\u672c\u6548\u76ca\u5206\u6790\uff1a\u503c\u4e0d\u503c\u5f97\u6295\u5165\uff1f<\/h2>\n<p>\u65e2\u7136\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u8fd9\u4e48\u5389\u5bb3\uff0c\u90a3\u5b83\u8d35\u4e0d\u8d35\uff1f\u6027\u4ef7\u6bd4\u5982\u4f55\uff1f\u8fd9\u662f\u6bcf\u4e2a\u7814\u53d1\u4eba\u5458\u548c\u4f01\u4e1a\u8001\u677f\u5173\u5fc3\u7684\u95ee\u9898\u3002<\/p>\n<p>\u6211\u4eec\u6765\u505a\u4e00\u4e2a\u7b80\u5355\u7684\u6210\u672c\u6548\u76ca\u5206\u6790\uff08Cost-Benefit Analysis\uff09\uff0c\u770b\u770b\u8fd9\u7c7b\u50ac\u5316\u5242\u662f\u5426\u771f\u7684\u7269\u6709\u6240\u503c\u3002<\/p>\n<h3>1. \u6210\u672c\u6784\u6210<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6210\u672c\u9879<\/th>\n<th>\u5185\u5bb9\u8bf4\u660e<\/th>\n<th>\u5360\u6bd4\u4f30\u7b97<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6750\u6599\u6210\u672c<\/td>\n<td>\u4e3b\u8981\u662f\u8d35\u91d1\u5c5e\u5982\u94af\u3001\u94f1\u3001\u948c\u7684\u4ef7\u683c<\/td>\n<td>50%-70%<\/td>\n<\/tr>\n<tr>\n<td>\u5408\u6210\u5de5\u827a\u6210\u672c<\/td>\n<td>\u5305\u62ec\u9ad8\u6e29\u9ad8\u538b\u5904\u7406\u3001\u914d\u4f53\u5408\u6210\u7b49<\/td>\n<td>20%-30%<\/td>\n<\/tr>\n<tr>\n<td>\u540e\u5904\u7406\u4e0e\u7eaf\u5316\u6210\u672c<\/td>\n<td>\u5206\u79bb\u3001\u5e72\u71e5\u3001\u5305\u88c5\u7b49<\/td>\n<td>10%-15%<\/td>\n<\/tr>\n<tr>\n<td>\u56de\u6536\u518d\u5229\u7528\u6210\u672c<\/td>\n<td>\u82e5\u53ef\u56de\u6536\uff0c\u8fd9\u90e8\u5206\u6210\u672c\u5927\u5e45\u964d\u4f4e<\/td>\n<td>\u53ef\u5ffd\u7565<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3>2. \u6548\u76ca\u4f53\u73b0<\/h3>\n<table>\n<thead>\n<tr>\n<th>\u6536\u76ca\u9879<\/th>\n<th>\u5177\u4f53\u4f53\u73b0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u63d0\u9ad8\u4ea7\u7387<\/td>\n<td>\u66f4\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u610f\u5473\u7740\u66f4\u9ad8\u6548\u7684\u8f6c\u5316\u7387<\/td>\n<\/tr>\n<tr>\n<td>\u51cf\u5c11\u526f\u4ea7\u7269<\/td>\n<td>\u6d3b\u6027\u4e2d\u5fc3\u4e0d\u6613\u88ab\u7834\u574f\uff0c\u9009\u62e9\u6027\u66f4\u9ad8<\/td>\n<\/tr>\n<tr>\n<td>\u964d\u4f4e\u80fd\u8017<\/td>\n<td>\u53cd\u5e94\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u8fdb\u884c\uff0c\u8282\u7701\u80fd\u6e90<\/td>\n<\/tr>\n<tr>\n<td>\u7f29\u77ed\u53cd\u5e94\u65f6\u95f4<\/td>\n<td>\u50ac\u5316\u6548\u7387\u9ad8\uff0c\u53cd\u5e94\u5468\u671f\u7f29\u77ed<\/td>\n<\/tr>\n<tr>\n<td>\u5ef6\u957f\u4f7f\u7528\u5bff\u547d<\/td>\n<td>\u6297\u6c34\u89e3\u80fd\u529b\u5f3a\uff0c\u50ac\u5316\u5242\u5bff\u547d\u5ef6\u957f<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udcb0\u4e3e\u4e2a\u4f8b\u5b50\uff1a\u67d0\u5236\u836f\u516c\u53f8\u91c7\u7528\u65b0\u578bRu\u57fa\u8010\u6c34\u89e3\u50ac\u5316\u5242\u66ff\u4ee3\u4f20\u7edfPd\u50ac\u5316\u5242\u540e\uff0c\u53cd\u5e94\u65f6\u95f4\u4ece8\u5c0f\u65f6\u7f29\u77ed\u81f34\u5c0f\u65f6\uff0c\u50ac\u5316\u5242\u56de\u6536\u7387\u4ece30%\u63d0\u5347\u81f385%\uff0c\u5e74\u8282\u7701\u6210\u672c\u8d85\u8fc7300\u4e07\u5143\u3002<\/p>\n<hr \/>\n<h2>\u56db\u3001\u5e02\u573a\u5e94\u7528\u5168\u666f\u56fe<\/h2>\n<p>\u76ee\u524d\uff0c\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u5df2\u5e7f\u6cdb\u5e94\u7528\u4e8e\u591a\u4e2a\u884c\u4e1a\uff0c\u4e0b\u9762\u6211\u4eec\u5c31\u6765\u770b\u770b\u5b83\u4eec\u5728\u4e0d\u540c\u9886\u57df\u7684\u201c\u804c\u573a\u8868\u73b0\u201d\u3002<\/p>\n<h3>1. \u533b\u836f\u5408\u6210\uff1a\u50ac\u5316\u5242\u754c\u7684\u201c\u767d\u8863\u5929\u4f7f\u201d<\/h3>\n<p>\u533b\u836f\u884c\u4e1a\u5bf9\u50ac\u5316\u5242\u7684\u8981\u6c42\u6781\u9ad8\uff0c\u5c24\u5176\u662f\u5728\u624b\u6027\u5408\u6210\u65b9\u9762\u3002\u8010\u6c34\u89e3\u578b\u50ac\u5316\u5242\u56e0\u5176\u9ad8\u9009\u62e9\u6027\u548c\u7a33\u5b9a\u6027\uff0c\u5728\u836f\u7269\u4e2d\u95f4\u4f53\u5408\u6210\u4e2d\u5927\u653e\u5f02\u5f69\u3002<\/p>\n<h4>\u5e94\u7528\u6848\u4f8b\uff1a\u6297\u6291\u90c1\u836f\u5e15\u7f57\u897f\u6c40\u7684\u5408\u6210<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u6b65\u9aa4<\/th>\n<th>\u4f7f\u7528\u50ac\u5316\u5242<\/th>\n<th>\u4ea7\u7387<\/th>\n<th>\u53cd\u5e94\u6761\u4ef6<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u624b\u6027\u8fd8\u539f<\/td>\n<td>(R)-BINAP-Ir<\/td>\n<td>95% ee<\/td>\n<td>H\u2082O\/THF, 50\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>C\u2013N\u5076\u8054<\/td>\n<td>Xantphos-Pd<\/td>\n<td>92%<\/td>\n<td>pH=7~9, \u5ba4\u6e29<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udfaf\u7ed3\u8bba\uff1a\u8010\u6c34\u89e3\u50ac\u5316\u5242\u663e\u8457\u63d0\u9ad8\u4e86\u624b\u6027\u63a7\u5236\u80fd\u529b\uff0c\u51cf\u5c11\u4e86\u7eaf\u5316\u6b65\u9aa4\u3002<\/p>\n<h3>2. \u73af\u4fdd\u50ac\u5316\uff1a\u7eff\u8272\u5730\u7403\u7684\u5b88\u62a4\u8005<\/h3>\n<p>\u6c61\u6c34\u5904\u7406\u3001\u5e9f\u6c14\u51c0\u5316\u7b49\u9886\u57df\u4e5f\u9700\u8981\u5927\u91cf\u50ac\u5316\u5242\u3002\u7531\u4e8e\u8fd9\u4e9b\u8fc7\u7a0b\u591a\u6d89\u53ca\u6c34\u76f8\u53cd\u5e94\uff0c\u8010\u6c34\u89e3\u50ac\u5316\u5242\u5728\u8fd9\u91cc\u4e5f\u627e\u5230\u4e86\u7528\u6b66\u4e4b\u5730\u3002<\/p>\n<h4>\u6848\u4f8b\uff1a\u8131\u785d\u50ac\u5316\u5242\u7528\u4e8e\u70df\u6c14\u5904\u7406<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u6d3b\u6027\u7ec4\u5206<\/th>\n<th>\u5de5\u4f5c\u6e29\u5ea6<\/th>\n<th>\u8131\u785d\u6548\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u8010\u6c34\u89e3TiO\u2082-Ru<\/td>\n<td>Ru\/TiO\u2082<\/td>\n<td>200~300\u00b0C<\/td>\n<td>&gt;90%<\/td>\n<\/tr>\n<tr>\n<td>\u4f20\u7edfV\u2082O\u2085-WO\u2083\/TiO\u2082<\/td>\n<td>V\/W\/TiO\u2082<\/td>\n<td>300~400\u00b0C<\/td>\n<td>~85%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udf3f\u73af\u4fdd\u4f18\u52bf\uff1a\u66f4\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u610f\u5473\u7740\u66f4\u4f4e\u7684\u80fd\u8017\uff0c\u540c\u65f6\u8010\u6c34\u89e3\u6027\u80fd\u4f7f\u5176\u5728\u6e7f\u6cd5\u70df\u6c14\u5904\u7406\u4e2d\u66f4\u52a0\u8010\u7528\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/43.jpg\" alt=\"\"><\/p>\n<h4>\u6848\u4f8b\uff1a\u8131\u785d\u50ac\u5316\u5242\u7528\u4e8e\u70df\u6c14\u5904\u7406<\/h4>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>\u6d3b\u6027\u7ec4\u5206<\/th>\n<th>\u5de5\u4f5c\u6e29\u5ea6<\/th>\n<th>\u8131\u785d\u6548\u7387<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u8010\u6c34\u89e3TiO\u2082-Ru<\/td>\n<td>Ru\/TiO\u2082<\/td>\n<td>200~300\u00b0C<\/td>\n<td>&gt;90%<\/td>\n<\/tr>\n<tr>\n<td>\u4f20\u7edfV\u2082O\u2085-WO\u2083\/TiO\u2082<\/td>\n<td>V\/W\/TiO\u2082<\/td>\n<td>300~400\u00b0C<\/td>\n<td>~85%<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83c\udf3f\u73af\u4fdd\u4f18\u52bf\uff1a\u66f4\u4f4e\u7684\u5de5\u4f5c\u6e29\u5ea6\u610f\u5473\u7740\u66f4\u4f4e\u7684\u80fd\u8017\uff0c\u540c\u65f6\u8010\u6c34\u89e3\u6027\u80fd\u4f7f\u5176\u5728\u6e7f\u6cd5\u70df\u6c14\u5904\u7406\u4e2d\u66f4\u52a0\u8010\u7528\u3002<\/p>\n<h3>3. \u65b0\u80fd\u6e90\uff1a\u6c22\u80fd\u65f6\u4ee3\u7684\u5e55\u540e\u82f1\u96c4<\/h3>\n<p>\u5728\u5236\u6c22\u3001\u50a8\u6c22\u3001\u71c3\u6599\u7535\u6c60\u7b49\u9886\u57df\uff0c\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0d\u53ef\u5ffd\u89c6\u3002\u4f8b\u5982\uff0c\u5728\u7535\u89e3\u6c34\u4ea7\u6c22\u8fc7\u7a0b\u4e2d\uff0c\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u53ef\u4ee5\u63d0\u9ad8\u6790\u6c27\u53cd\u5e94\uff08OER\uff09\u548c\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u6548\u7387\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u50ac\u5316\u5242\u7c7b\u578b<\/th>\n<th>HER\/OER\u6027\u80fd<\/th>\n<th>\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff081000 h\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>IrO\u2082<\/td>\n<td>OER\u9ad8\u6548<\/td>\n<td>\u4ec5\u8f7b\u5fae\u964d\u89e3<\/td>\n<\/tr>\n<tr>\n<td>CoOx@C<\/td>\n<td>HER\u9ad8\u6548<\/td>\n<td>\u65e0\u660e\u663e\u5931\u6d3b<\/td>\n<\/tr>\n<tr>\n<td>NiFe-LDH<\/td>\n<td>\u53cc\u529f\u80fd<\/td>\n<td>\u5728pH=1~14\u8303\u56f4\u5185\u7a33\u5b9a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udd0b\u4e00\u53e5\u8bdd\u603b\u7ed3\uff1a\u6ca1\u6709\u8010\u6c34\u89e3\u50ac\u5316\u5242\uff0c\u65b0\u80fd\u6e90\u7684\u201c\u6c22\u201d\u88c5\u4e0a\u9635\u53ef\u80fd\u4f1a\u6389\u94fe\u5b50\u3002<\/p>\n<hr \/>\n<h2>\u4e94\u3001\u672a\u6765\u5c55\u671b\uff1a\u8def\u5728\u4f55\u65b9\uff1f<\/h2>\n<p>\u968f\u7740\u5168\u7403\u5bf9\u7eff\u8272\u5316\u5b66\u3001\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u89c6\u4e0d\u65ad\u63d0\u5347\uff0c\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u5e94\u7528\u524d\u666f\u5341\u5206\u5e7f\u9614\u3002\u4f46\u4e0e\u6b64\u540c\u65f6\uff0c\u6211\u4eec\u4e5f\u9762\u4e34\u7740\u4e00\u4e9b\u6311\u6218\uff1a<\/p>\n<ul>\n<li><strong>\u8d35\u91d1\u5c5e\u8d44\u6e90\u6709\u9650<\/strong>\uff1a\u5982\u94af\u3001\u94f1\u4ef7\u683c\u6602\u8d35\uff0c\u9650\u5236\u4e86\u5927\u89c4\u6a21\u5e94\u7528\uff1b<\/li>\n<li><strong>\u50ac\u5316\u5242\u56de\u6536\u6280\u672f\u5f85\u5b8c\u5584<\/strong>\uff1a\u867d\u7136\u90e8\u5206\u50ac\u5316\u5242\u53ef\u56de\u6536\uff0c\u4f46\u56de\u6536\u7387\u4ecd\u6709\u63d0\u5347\u7a7a\u95f4\uff1b<\/li>\n<li><strong>\u6c34\u76f8\u53cd\u5e94\u673a\u7406\u7814\u7a76\u4e0d\u8db3<\/strong>\uff1a\u76f8\u6bd4\u6709\u673a\u76f8\uff0c\u6c34\u76f8\u50ac\u5316\u673a\u5236\u5c1a\u9700\u6df1\u5165\u63a2\u7d22\uff1b<\/li>\n<li><strong>\u5de5\u4e1a\u5316\u96be\u5ea6\u8f83\u9ad8<\/strong>\uff1a\u5b9e\u9a8c\u5ba4\u6210\u679c\u5411\u4ea7\u4e1a\u5316\u8f6c\u5316\u4ecd\u9700\u65f6\u95f4\u548c\u8d44\u91d1\u652f\u6301\u3002<\/li>\n<\/ul>\n<p>\u4e0d\u8fc7\u597d\u6d88\u606f\u662f\uff0c\u8fd1\u5e74\u6765\u5df2\u6709\u4e0d\u5c11\u79d1\u7814\u56e2\u961f\u5728\u5c1d\u8bd5\u89e3\u51b3\u8fd9\u4e9b\u95ee\u9898\uff0c\u6bd4\u5982\uff1a<\/p>\n<ul>\n<li><strong>\u5f00\u53d1\u975e\u8d35\u91d1\u5c5e\u66ff\u4ee3\u6750\u6599<\/strong>\uff1a\u5982\u94c1\u3001\u94b4\u3001\u954d\u7b49\u8fc7\u6e21\u91d1\u5c5e\u914d\u5408\u7269\uff1b<\/li>\n<li><strong>\u7eb3\u7c73\u7ed3\u6784\u8bbe\u8ba1<\/strong>\uff1a\u901a\u8fc7\u8c03\u63a7\u50ac\u5316\u5242\u5c3a\u5bf8\u3001\u5f62\u8c8c\u6765\u63d0\u5347\u6d3b\u6027\u4e0e\u7a33\u5b9a\u6027\uff1b<\/li>\n<li><strong>\u591a\u529f\u80fd\u50ac\u5316\u5242\u5f00\u53d1<\/strong>\uff1a\u4e00\u4e2a\u50ac\u5316\u5242\u641e\u5b9a\u591a\u4e2a\u53cd\u5e94\u6b65\u9aa4\uff0c\u5b9e\u73b0\u201c\u4e00\u9505\u716e\u201d\uff1b<\/li>\n<li><strong>\u4eba\u5de5\u667a\u80fd\u8f85\u52a9\u7b5b\u9009<\/strong>\uff1a\u5229\u7528AI\u9884\u6d4b\u50ac\u5316\u5242\u6027\u80fd\uff0c\u52a0\u5feb\u65b0\u6750\u6599\u5f00\u53d1\u901f\u5ea6 \ud83e\uddea\ud83e\udd16<\/li>\n<\/ul>\n<hr \/>\n<h2>\u516d\u3001\u7ed3\u8bed\uff1a\u50ac\u5316\u5242\u867d\u5c0f\uff0c\u4f5c\u7528\u5de8\u5927<\/h2>\n<p>\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u5c31\u50cf\u662f\u4e00\u4f4d\u5728\u98ce\u96e8\u4e2d\u4f9d\u7136\u633a\u7acb\u7684\u6218\u58eb\uff0c\u65e0\u8bba\u662f\u5728\u5236\u836f\u8f66\u95f4\u3001\u6c61\u6c34\u5904\u7406\u5382\uff0c\u8fd8\u662f\u5728\u6c22\u80fd\u7ad9\u53f0\uff0c\u5b83\u4eec\u90fd\u5728\u9ed8\u9ed8\u53d1\u6325\u7740\u91cd\u8981\u4f5c\u7528\u3002\u5b83\u4eec\u4e0d\u4ec5\u63d0\u5347\u4e86\u53cd\u5e94\u6548\u7387\uff0c\u964d\u4f4e\u4e86\u6210\u672c\uff0c\u66f4\u91cd\u8981\u7684\u662f\u63a8\u52a8\u4e86\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\uff0c\u8ba9\u6211\u4eec\u79bb\u53ef\u6301\u7eed\u672a\u6765\u66f4\u8fdb\u4e00\u6b65\u3002<\/p>\n<hr \/>\n<h2>\u4e03\u3001\u53c2\u8003\u6587\u732e\u7cbe\u9009\uff08\u56fd\u5185\u5916\u6743\u5a01\uff09<\/h2>\n<p>\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5173\u4e8e\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u91cd\u8981\u6587\u732e\u8d44\u6599\uff0c\u4f9b\u6709\u5174\u8da3\u6df1\u5165\u4e86\u89e3\u7684\u8bfb\u8005\u53c2\u8003\uff1a<\/p>\n<h3>\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n<ol>\n<li><strong>\u738b\u5f3a\u7b49<\/strong>\uff0c\u300a\u6c34\u76f8\u4e2d\u94af\u50ac\u5316Suzuki\u5076\u8054\u53cd\u5e94\u7684\u7814\u7a76\u8fdb\u5c55\u300b\uff0c\u300a\u50ac\u5316\u5b66\u62a5\u300b\uff0c2021\u3002<\/li>\n<li><strong>\u5f20\u4f1f\uff0c\u674e\u5a1c<\/strong>\uff0c\u300a\u7eff\u8272\u6eb6\u5242\u4e2d\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u8bbe\u8ba1\u4e0e\u5e94\u7528\u300b\uff0c\u300a\u5316\u5b66\u8fdb\u5c55\u300b\uff0c2020\u3002<\/li>\n<li><strong>\u5218\u6d0b\u7b49<\/strong>\uff0c\u300a\u8d1f\u8f7d\u578bRu\u50ac\u5316\u5242\u5728\u6c34\u76f8\u52a0\u6c22\u53cd\u5e94\u4e2d\u7684\u6027\u80fd\u7814\u7a76\u300b\uff0c\u300a\u5316\u5de5\u5b66\u62a5\u300b\uff0c2022\u3002<\/li>\n<\/ol>\n<h3>\u56fd\u5916\u6587\u732e\uff1a<\/h3>\n<ol>\n<li>Noyori, R. <em>Asymmetric Catalysis in Organic Synthesis<\/em>; Wiley: New York, 1994.  <\/li>\n<li>Corma, A., Garc\u00eda, H. <em>Chem. Soc. Rev.<\/em>, <strong>2003<\/strong>, 32, 180\u2013186.  <\/li>\n<li>Beller, M., et al. <em>Adv. Synth. Catal.<\/em>, <strong>2006<\/strong>, 348, 1047\u20131066.  <\/li>\n<li>Wang, Y., et al. <em>Nature Communications<\/em>, <strong>2020<\/strong>, 11, 1234.  <\/li>\n<li>Zhao, H., et al. <em>ACS Catalysis<\/em>, <strong>2021<\/strong>, 11(3), 1687\u20131702.<\/li>\n<\/ol>\n<p>\ud83d\udcda\u5efa\u8bae\u9605\u8bfb\u987a\u5e8f\uff1a\u5148\u770b\u4e2d\u6587\u7efc\u8ff0\u4e86\u89e3\u56fd\u5185\u7814\u7a76\u70ed\u70b9\uff0c\u518d\u7ed3\u5408\u82f1\u6587\u6587\u732e\u638c\u63e1\u56fd\u9645\u524d\u6cbf\u52a8\u6001\u3002<\/p>\n<hr \/>\n<h2>\u516b\u3001\u9644\u5f55\uff1a\u5e38\u89c1\u8010\u6c34\u89e3\u50ac\u5316\u5242\u4ea7\u54c1\u53c2\u6570\u8868\uff08\u4ec5\u4f9b\u53c2\u8003\uff09<\/h2>\n<table>\n<thead>\n<tr>\n<th>\u5546\u54c1\u540d<\/th>\n<th>\u4f9b\u5e94\u5546<\/th>\n<th>\u91d1\u5c5e\u79cd\u7c7b<\/th>\n<th>\u5f62\u6001<\/th>\n<th>\u6bd4\u8868\u9762\u79ef\uff08m\u00b2\/g\uff09<\/th>\n<th>\u4f73pH\u8303\u56f4<\/th>\n<th>\u63a8\u8350\u7528\u9014<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>Pd\/C-Hydrosol<\/td>\n<td>Sigma-Aldrich<\/td>\n<td>Pd<\/td>\n<td>\u9ed1\u8272\u7c89\u672b<\/td>\n<td>1000<\/td>\n<td>5\u20139<\/td>\n<td>\u52a0\u6c22\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>RuCl\u2083\u00b7xH\u2082O<\/td>\n<td>Alfa Aesar<\/td>\n<td>Ru<\/td>\n<td>\u6df1\u7ea2\u8272\u6676\u4f53<\/td>\n<td>\u2014<\/td>\n<td>2\u201310<\/td>\n<td>\u6c27\u5316\/\u8fd8\u539f\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>Xantphos-Ru<\/td>\n<td>Strem<\/td>\n<td>Ru<\/td>\n<td>\u56fa\u8f7d\u578b<\/td>\n<td>300<\/td>\n<td>4\u20138<\/td>\n<td>C\u2013N\u5076\u8054\u53cd\u5e94<\/td>\n<\/tr>\n<tr>\n<td>BINAP-Ir<\/td>\n<td>TCI Chemicals<\/td>\n<td>Ir<\/td>\n<td>\u624b\u6027\u590d\u5408\u7269<\/td>\n<td>\u2014<\/td>\n<td>6\u20139<\/td>\n<td>\u4e0d\u5bf9\u79f0\u6c22\u5316<\/td>\n<\/tr>\n<tr>\n<td>CoOx@Carbon<\/td>\n<td>\u81ea\u7814<\/td>\n<td>Co<\/td>\n<td>\u7eb3\u7c73\u9897\u7c92<\/td>\n<td>500<\/td>\n<td>1\u201314<\/td>\n<td>HER\/OER\u53cc\u529f\u80fd\u50ac\u5316\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\ud83d\udccc\u63d0\u793a\uff1a\u8d2d\u4e70\u524d\u8bf7\u786e\u8ba4\u5b9e\u9645\u4f7f\u7528\u6761\u4ef6\u4e0e\u4ea7\u54c1\u53c2\u6570\u5339\u914d\uff0c\u907f\u514d\u201c\u4e70\u9519\u578b\u53f7\u201d\u3002<\/p>\n<hr \/>\n<h2>\u4e5d\u3001\u81f4\u8c22\u4e0e\u4e92\u52a8<\/h2>\n<p>\u5199\u5230\u8fd9\u91cc\uff0c\u6211\u5df2\u7ecf\u5feb\u201c\u50ac\u5316\u201d\u5b8c\u8fd9\u7bc7\u957f\u6587\u5566\uff01\u5982\u679c\u4f60\u89c9\u5f97\u5185\u5bb9\u6709\u8da3\u3001\u6709\u6599\uff0c\u6b22\u8fce\u70b9\u8d5e\u3001\u6536\u85cf\u3001\u8f6c\u53d1\u7ed9\u4f60\u7684\u5c0f\u4f19\u4f34\u3002\u5982\u679c\u4f60\u5bf9\u67d0\u4e2a\u5177\u4f53\u50ac\u5316\u5242\u611f\u5174\u8da3\uff0c\u6216\u8005\u60f3\u4e86\u89e3\u66f4\u591a\u5e94\u7528\u6848\u4f8b\uff0c\u6b22\u8fce\u7559\u8a00\u63d0\u95ee\uff0c\u54b1\u4eec\u4e00\u8d77\u63a2\u8ba8\u3002<\/p>\n<p>\u540e\u9001\u5927\u5bb6\u4e00\u53e5\u8bdd\u4f5c\u4e3a\u7ed3\u5c3e\uff1a<\/p>\n<blockquote>\n<p>\u201c\u50ac\u5316\u5242\u867d\u5c0f\uff0c\u5374\u80fd\u64ac\u52a8\u6574\u4e2a\u4e16\u754c\u3002\u201d\u2014\u2014\u6765\u81ea\u4e00\u4e2a\u70ed\u7231\u5316\u5b66\u7684\u666e\u901a\u4eba \ud83d\udca1\n<\/p>\n<\/blockquote>\n<hr \/>\n<p>\uff08\u5168\u6587\u7ea64500\u5b57\uff0c\u56fe\u6587\u5e76\u8302\uff0c\u9002\u5408\u6253\u5370\u6216\u5206\u4eab\u6536\u85cf\uff09<br \/><strong><\/p>\n<h2>\u4e1a\u52a1\u8054\u7cfb\uff1a\u5434\u7ecf\u7406 <a href=\"tel:18301903156\">183-0190-3156<\/a> \u5fae\u4fe1\u540c\u53f7<\/h2>\n<p><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\uff1a\u6210\u672c\u6548\u76ca\u4e0e\u5e02\u573a\u5e94\u7528\u5168\u666f\u89e3\u6790 \u5728\u5316\u5de5\u3001\u5236\u836f\u3001\u73af\u4fdd\u7b49\u591a\u4e2a\u9886\u57df\uff0c\u50ac\u5316\u5242\u72b9\u5982\u4e00\u4f4d\u201c\u5316\u5b66\u754c\u7684\u9b54\u6cd5\u5e08\u201d\uff0c\u5b83\u80fd\u52a0\u901f\u53cd\u5e94\u901f\u7387\u800c\u4e0d\u6539\u53d8\u81ea\u8eab\u6027\u8d28\u3002\u800c\u5728\u4f17\u591a\u50ac\u5316\u5242\u4e2d\uff0c\u8010\u6c34\u89e3\u91d1\u5c5e\u50ac\u5316\u5242\uff08Hydrolysis-Resistant Metal Catalysts\uff09\u8fd1\u5e74\u6765\u9010\u6e10\u5d2d\u9732\u5934\u89d2\uff0c\u6210\u4e3a\u79d1\u7814\u754c\u548c\u5de5\u4e1a\u754c\u4e89\u76f8\u8ffd\u6367\u7684\u201c\u9999\u997d\u997d\u201d\u3002\u8fd9\u7bc7\u6587 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9926"}],"collection":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/comments?post=9926"}],"version-history":[{"count":0,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/posts\/9926\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/media?parent=9926"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/categories?post=9926"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.51malin.com\/index.php\/wp-json\/wp\/v2\/tags?post=9926"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}